Tetrachlorido(1,10-phenanthroline-κ2 N,N′)platinum(IV) monohydrate
نویسندگان
چکیده
In the title complex, [PtCl(4)(C(12)H(8)N(2))]·H(2)O, the Pt(4+) ion is six-coordinated in a distorted octa-hedral environment by two N atoms of a 1,10-phenanthroline ligand and by four Cl atoms. As a result of the different trans effects of the N and Cl atoms, the Pt-Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays inter-molecular π-π inter-actions between the six-membered rings, with a centroid-centroid distance of 3.834 Å. There are also weak intra-molecular C-H⋯Cl hydrogen bonds. According to the IR spectrum, solvent water was present in the crystal, but owing to the high thermal motion of the uncoordinated O atom, the H atoms could not be detected.
منابع مشابه
Tetrachlorido(1,10-phenanthroline-κ2 N,N′)platinum(IV) acetonitrile hemisolvate
The asymmetric unit of the title compound, [PtCl(4)(C(12)H(8)N(2))]·0.5CH(3)CN, contains two crystallographically independent Pt(IV) complexes with very similar geometry and one solvent mol-ecule. In the complexes, each Pt(IV) ion is six-coordinated in a distorted octa-hedral environment by two N atoms of the 1,10-phenanthroline ligand and four Cl atoms. Because of the different trans effects o...
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